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Consider the following general structure. Consider the following general structure.   Positions 1,4 and 2,6 and 3,5 are termed para, ortho, and meta, respectively. Positions 1,4 and 2,6 and 3,5 are termed para, ortho, and meta, respectively.

A) True
B) False

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Which of the following molecules is the most acidic? Which of the following molecules is the most acidic?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) A) and D)
F) B) and D)

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Consider the following structures, Consider the following structures,   A B Structure A is more acidic than B. A B Structure A is more acidic than B.

A) True
B) False

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Which of the following is true about [10]annulene? Which of the following is true about [10]annulene?   A)  [10]annulene is planar B)  [10]annulene is nonaromatic C)  [10]annulene undergoes addition reactions similar to simple alkenes D)  [10]annulene has 10 pi electrons


A) [10]annulene is planar
B) [10]annulene is nonaromatic
C) [10]annulene undergoes addition reactions similar to simple alkenes
D) [10]annulene has 10 pi electrons

E) B) and D)
F) None of the above

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Which of the following is not one of HΓΌckel's criteria for aromaticity?


A) The compound must be cyclic
B) The compound must have one p-orbital on each atom of a ring
C) The compound must be planar or nearly planar so that there is a continuous overlap of p orbitals
D) The compound must have a closed loop of six pi electrons

E) B) and C)
F) B) and D)

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What is the chemical name of the following compound? ​ What is the chemical name of the following compound? ​   A)  2,3-dichloro-5,6-dicyano-1,4-benzoquinone B)  2,3-dichloro-5,6-dicyano-1,4-benzodione C)  5,6-dicyano-2,3-dichloro-1,4-benzodione D)  2,3-dicyano-5,6-dichloro-1,4-benzoquinone


A) 2,3-dichloro-5,6-dicyano-1,4-benzoquinone
B) 2,3-dichloro-5,6-dicyano-1,4-benzodione
C) 5,6-dicyano-2,3-dichloro-1,4-benzodione
D) 2,3-dicyano-5,6-dichloro-1,4-benzoquinone

E) A) and B)
F) A) and D)

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Which of the following statements is not true about the structure of benzene?


A) the carbon-carbon bonds are all the same length
B) the structure rapidly transforms between two resonance contributors
C) the structure is an average of two resonance contributors
D) the ring of six carbon atoms is planar

E) A) and B)
F) A) and C)

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What are the relative positions of the substituents in the following structure? What are the relative positions of the substituents in the following structure?   A)  anti B)  meta C)  ortho D)  para


A) anti
B) meta
C) ortho
D) para

E) A) and D)
F) A) and C)

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Which of the following compounds undergoes heterolytic carbon-halogen bond cleavage to form a stable organic cation? Which of the following compounds undergoes heterolytic carbon-halogen bond cleavage to form a stable organic cation?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) C) and D)
F) A) and B)

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Which of the following heterocycles is not aromatic? Which of the following heterocycles is not aromatic?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) B) and C)
F) A) and B)

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Aspirin, also known as acetylsalicylic acid, is used to treat fever and inflammation. It is prepared from an unknown compound "A" by the process of esterification, using acetic anhydride. Identify compound "A".


A)
Aspirin, also known as acetylsalicylic acid, is used to treat fever and inflammation. It is prepared from an unknown compound  A  by the process of esterification, using acetic anhydride. Identify compound  A . A)    B)    C)    D)
B)
Aspirin, also known as acetylsalicylic acid, is used to treat fever and inflammation. It is prepared from an unknown compound  A  by the process of esterification, using acetic anhydride. Identify compound  A . A)    B)    C)    D)
C)
Aspirin, also known as acetylsalicylic acid, is used to treat fever and inflammation. It is prepared from an unknown compound  A  by the process of esterification, using acetic anhydride. Identify compound  A . A)    B)    C)    D)
D)
Aspirin, also known as acetylsalicylic acid, is used to treat fever and inflammation. It is prepared from an unknown compound  A  by the process of esterification, using acetic anhydride. Identify compound  A . A)    B)    C)    D)

E) None of the above
F) B) and C)

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The ______ substituent is affected during the oxidation of 2-bromo-4-nitrotoulene using chromic acid.


A) methyl
B) nitro
C) bromo
D) hydroxy

E) A) and B)
F) C) and D)

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What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) A) and B)
F) A) and C)

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Identify the major product of the following reaction. ​ Identify the major product of the following reaction. ​   A)    B)    C)    D)


A)
Identify the major product of the following reaction. ​   A)    B)    C)    D)
B)
Identify the major product of the following reaction. ​   A)    B)    C)    D)
C)
Identify the major product of the following reaction. ​   A)    B)    C)    D)
D)
Identify the major product of the following reaction. ​   A)    B)    C)    D)

E) A) and B)
F) A) and C)

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Which of the following represents the energy levels of the molecular orbitals of benzene? Which of the following represents the energy levels of the molecular orbitals of benzene?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) B) and C)
F) None of the above

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Furan has the structure shown below. Furan has the structure shown below.   The Ο€ orbitals in furan are shown below.  The Ο€ orbitals in furan are shown below. Furan has the structure shown below.   The Ο€ orbitals in furan are shown below.

A) True
B) False

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Which of the following has the compounds shown in the correct order of decreasing acidity (i.e., more acidic > less acidic) ? Which of the following has the compounds shown in the correct order of decreasing acidity (i.e., more acidic > less acidic) ?   A)  1 > 2 > 3 B)  2 > 3 > 1 C)  3 > 2 > 1 D)  1 > 3 > 2


A) 1 > 2 > 3
B) 2 > 3 > 1
C) 3 > 2 > 1
D) 1 > 3 > 2

E) B) and D)
F) B) and C)

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