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he amount of energy in infrared light corresponds to the amount of energy needed to increase certain molecular motions, such as bond vibrations, in organic molecules.

A) True
B) False

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Which of the following bonds gives rise to an absorbance at approximately 2700-3300 cm−1 in the infrared spectrum?


A) C≡C
B) C=O
C) C=C
D) C−H

E) B) and D)
F) All of the above

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What is the energy of a photon moving with a frequency of 10.0 × 1010 s−1? (Planck's constant = 6.626 × 10−34 J s)


A) 6.626 × 10−23 J
B) 6.626 × 10−22 J
C) 66.26 × 10−23 J
D) 66.26 × 10−25 J

E) B) and C)
F) A) and D)

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Which of the following bonds gives the weakest peak in the infrared spectrum for a stretching vibration? Which of the following bonds gives the weakest peak in the infrared spectrum for a stretching vibration?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) None of the above
F) C) and D)

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Which of the following compounds gives an infrared spectrum with peaks at 3300 cm−1 (sharp peak) and 2150 cm−1 (sharp peak) ? Which of the following compounds gives an infrared spectrum with peaks at 3300 cm−<sup>1</sup> (sharp peak)  and 2150 cm−<sup>1</sup> (sharp peak) ?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) A) and D)
F) C) and D)

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Which of the following compounds gives an infrared spectrum with peaks at 1000-1250 cm−1 (strong) , but does not have peaks at 3200-3650 or 1630-1820 cm−1 (sharp, weak peak) ? Which of the following compounds gives an infrared spectrum with peaks at 1000-1250 cm−<sup>1</sup> (strong) , but does not have peaks at 3200-3650 or 1630-1820 cm−<sup>1</sup> (sharp, weak peak) ?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) A) and B)
F) A) and C)

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Cyclohexene and 2-hexyne both have the molecular formula C6H10. Any of the following regions of an IR spectrum could be used to distinguish these two compounds. 3020-3100 cm−1 2100-2260 cm−1 1650-1670 cm−1

A) True
B) False

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Which of the following relationships is not valid as applied to infrared spectroscopy?


A) wavenumber = 1/λ (in cm)
B) ΔE = h ν
C) ΔE = λ ν
D) ν = 4.12 √(K/μ)

E) B) and D)
F) A) and C)

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Which of the following compounds gives a carbonyl bond absorption at the lowest frequency? Which of the following compounds gives a carbonyl bond absorption at the lowest frequency?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) A) and C)
F) None of the above

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An IR spectrum of an unknown organic molecule having the formula which contains carbon, hydrogen, and oxygen reveals a strong absorption at 1715-1725 cm-1. This molecule is most likely an ether.

A) True
B) False

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Which of the following compounds gives a carbonyl bond absorption at the highest frequency? Which of the following compounds gives a carbonyl bond absorption at the highest frequency?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) B) and C)
F) A) and B)

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What is the frequency of a radiation with a wavelength of 3.0 × 10−5 m? (Speed of light = 3.0 × 108 m/s)


A) 1 × 1013 Hz
B) 2 × 1013 Hz
C) 1.1 × 1013 Hz
D) 1.2 × 1013 Hz

E) All of the above
F) A) and D)

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Label three peaks in the following spectrum with the bond that gives rise to them, and identify the functional group that is present in the compound (the compound has a formula of C5H10O2)? ​ Label three peaks in the following spectrum with the bond that gives rise to them, and identify the functional group that is present in the compound (the compound has a formula of C<sub>5</sub>H<sub>10</sub>O<sub>2</sub>)? ​

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O-H: 3000-3600 cm-1
C-...

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Which of the following regions in the electromagnetic spectrum corresponds to the radiation with the highest energy?


A) radio waves
B) ultraviolet
C) infrared
D) visible

E) None of the above
F) All of the above

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