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The following molecules all contain the same functional group except 2. 1.CH3OH 2.CH3OCH3 3.CH3CH2OH 4.CH3CH(OH)CH3

A) True
B) False

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Convert the following structure into a bond-line drawing. Convert the following structure into a bond-line drawing.

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Consider the following structural formula. Consider the following structural formula.   The following is a resonance structure.  The following is a resonance structure. Consider the following structural formula.   The following is a resonance structure.

A) True
B) False

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Which of the following species possesses a formal charge?


A) BH3
B) BH4
C) CCl4
D) H2S

E) None of the above
F) A) and D)

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Which of the following is a primary (1°) amine? Which of the following is a primary (1°)  amine?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) None of the above
F) A) and B)

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Which atomic orbitals overlap to form the carbon-hydrogen σ bonding molecular orbitals of ethene, H2C=CH2?


A) C2p + H1s
B) C2sp + H1s
C) C2sp2 + H1s
D) C2sp3 + H1s

E) A) and B)
F) B) and C)

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Which of the following is trigonal planar?


A) boron trifluoride, BF3
B) methyl anion, CH3
C) methane, CH4
D) ammonia, NH3

E) A) and B)
F) None of the above

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Draw bond-line structures of all of the primary (1°) alcohols that have the formula C5H12O.

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The hybridization on the numbered carbon atoms in the following compound would be Carbon 1 sp3 and Carbon 2 sp2. The hybridization on the numbered carbon atoms in the following compound would be Carbon 1 sp<sup>3</sup> and Carbon 2 sp<sup>2</sup>.

A) True
B) False

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Draw bond-line structures of all of the aldehydes that have the formula C5H10O.

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How many electrons are there in the valence shell of the carbon atom of a methyl cation, CH3+?


A) 4
B) 5
C) 6
D) 7

E) A) and C)
F) B) and C)

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Which of the following is a tertiary amine?


A) CH3CH2N(CH3) 2
B) (CH3) 3CNH2
C) CH3CH2NHCH3
D) CH3CH2NHCH(CH3) 2

E) A) and B)
F) A) and C)

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Draw bond-line structures of all of the alcohols that have the formula C4H10O.

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What is the approximate value of the H−C−H bond angles in methane, CH4?


A) 90°
B) 109°
C) 120°
D) 180°

E) All of the above
F) A) and B)

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Which of the following compounds is a ketone?


A) CH3CH2COOH
B) CH3CH2CHO
C) CH3CH2CH2OH
D) CH3COCH3

E) A) and B)
F) C) and D)

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Provide a neatly drawn figure to show the atomic orbitals that overlap to form each of the bonds in water (H2O) and which contain the lone pair of electrons. Label each orbital with its hybridization.

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Which of the following elements has the highest electronegativity?


A) C
B) P
C) Si
D) Cl

E) B) and C)
F) A) and C)

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How many electrons can the shell with a principal quantum number of 2 hold?


A) 1
B) 2
C) 4
D) 8

E) A) and B)
F) None of the above

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Which atomic orbitals overlap to form the C−O bond of dimethyl ether, (CH3) 2O?


A) C 2sp3 + O 2sp2
B) C 2sp2 + O 2p
C) C 2sp2 + O 2sp2
D) C 2sp3 + O 2sp3

E) A) and C)
F) B) and C)

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Consider the following molecular model.  Consider the following molecular model.   The condensed structural formula would be  \quad\quad\mathrm{CH}_{3} \quad\mathrm{CH}_{3}   \quad\quad\quad | \quad\quad\quad |  \mathrm{CH}_{3}-\mathrm{CH}-\mathrm{CH}-\mathrm{CH}_{3} The condensed structural formula would be \quad\quadCH3CH3\mathrm{CH}_{3} \quad\mathrm{CH}_{3} \quad\quad\quad | \quad\quad\quad | CH3CHCHCH3\mathrm{CH}_{3}-\mathrm{CH}-\mathrm{CH}-\mathrm{CH}_{3}

A) True
B) False

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