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Which of the following functional groups is likely to be present in a molecule that has peaks in the infrared spectrum at 3200-3650 cm-1 (strong) , but does not have peaks at 1630-1820 or 1000-1250 cm-1


A) alcohol
B) aldehyde or ketone
C) ether
D) ester

E) A) and C)
F) All of the above

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Which of the following bonds (circled) vibrates at the highest frequency? Which of the following bonds (circled)  vibrates at the highest frequency?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) A) and B)
F) B) and C)

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How could you distinguish between methyl butanoate and pentanoic acid by infrared spectroscopy? How could you distinguish between methyl butanoate and pentanoic acid by infrared spectroscopy?

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The infrared spectrum of penta...

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Which of the following bonds undergoes stretching at the highest frequency?


A) O-H
B) C-H
C) C=O
D) CºC

E) A) and B)
F) A) and C)

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Which of the following functional groups is likely to be present in a molecule that has peaks in the infrared spectrum at 1630-1820 cm-1 (strong, broad) , but does not have peaks at 3200-3650 or 1000-1250 cm-1


A) alcohol
B) aldehyde or ketone
C) ether
D) ester

E) B) and C)
F) None of the above

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Which of the following regions in the electromagnetic spectrum corresponds to the radiation with the highest energy?


A) radio waves
B) ultraviolet
C) infrared
D) visible

E) C) and D)
F) None of the above

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Which of the following compounds gives an infrared spectrum with a peak in the range of 1630-1820 cm-1 (strong peak) , but does not have peaks at 3200-3650 or 1000-1250 cm-1? Which of the following compounds gives an infrared spectrum with a peak in the range of 1630-1820 cm<sup>-1</sup> (strong peak) , but does not have peaks at 3200-3650 or 1000-1250 cm<sup>-1</sup>?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) A) and B)
F) A) and C)

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Which of the following bonds (circled) gives a very weak or no stretching absorption in the infrared spectrum? Which of the following bonds (circled)  gives a very weak or no stretching absorption in the infrared spectrum?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) A) and D)
F) None of the above

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Which of the following compounds gives an infrared spectrum with peaks at 1000-1250 cm-1 (strong) , but does not have peaks at 3200-3650 or 1630-1820 cm-1 (sharp, weak peak) ? Which of the following compounds gives an infrared spectrum with peaks at 1000-1250 cm<sup>-1</sup> (strong) , but does not have peaks at 3200-3650 or 1630-1820 cm<sup>-1</sup> (sharp, weak peak) ?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) A) and D)
F) C) and D)

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Provide the structure of four compounds with the molecular formula C5H10O which give a strong absorption peak at 1700-1740 cm-1 in the infrared spectrum, but no significant peaks at 1600-1640 cm-1 .

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Any four o...

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Which of the following compounds gives a carbonyl bond absorption at the highest frequency? Which of the following compounds gives a carbonyl bond absorption at the highest frequency?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) A) and D)
F) B) and D)

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Which of the following bonds undergoes stretching at the highest frequency?


A) C=O
B) C-O
C) C=C
D) C-C

E) None of the above
F) A) and B)

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Which of the following compounds gives a carbonyl bond absorption at the highest frequency? Which of the following compounds gives a carbonyl bond absorption at the highest frequency?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) B) and C)
F) All of the above

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Which of the following bonds gives rise to a strong absorbance at approximately 1630-1820 cm-1 in the infrared spectrum?


A) C=O
B) C-O
C) C=C
D) CºC

E) A) and B)
F) B) and C)

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Which of the following compounds gives an infrared spectrum with a peak at ~1750 cm-1, but no significant peaks at 3000-3500 cm-1 or 1050-1250 cm-1? Which of the following compounds gives an infrared spectrum with a peak at ~1750 cm<sup>-1</sup>, but no significant peaks at 3000-3500 cm<sup>-1</sup> or 1050-1250 cm<sup>-1</sup>?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) All of the above
F) None of the above

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Which of the following bonds (circled) gives the weakest absorbance in the infrared spectrum? Which of the following bonds (circled)  gives the weakest absorbance in the infrared spectrum?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) A) and B)
F) All of the above

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Which of the following bonds gives rise to an absorbance at approximately 2700-3300 cm-1 in the infrared spectrum?


A) CºC
B) C=O
C) C=C
D) C-H

E) A) and B)
F) A) and C)

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Which of the following compounds does not give an infrared spectrum with peak at ~1750 cm-1? Which of the following compounds does not give an infrared spectrum with peak at ~1750 cm<sup>-1</sup>?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) A) and B)
F) B) and D)

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Which of the following relationships is not valid as applied to infrared spectroscopy?


A) wavenumber = 1/l (in cm)
B) DE = h n
C) DE = l n
D) n = 4.12 Ö(K/m)

E) A) and B)
F) A) and C)

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Which of the following compounds gives an infrared spectrum with peaks in the ranges of 3200-3650 (strong, broad) , but does not have peaks at 1630-1820 (strong) or 1600-1640 cm-1 (medium) ? Which of the following compounds gives an infrared spectrum with peaks in the ranges of 3200-3650 (strong, broad) , but does not have peaks at 1630-1820 (strong)  or 1600-1640 cm<sup>-1</sup> (medium) ?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

E) B) and C)
F) A) and D)

Correct Answer

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