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Which of the following structures does not have a plane of symmetry? Which of the following structures does not have a plane of symmetry?   A) only 2 B) only 1 and 2 C) only 3 and 4 D) only 1, 2 and 4


A) only 2
B) only 1 and 2
C) only 3 and 4
D) only 1, 2 and 4

E) C) and D)
F) A) and D)

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How much of the R enantiomer is present in 10 g of a mixture which has an enantiomeric excess of 60% of the R isomer?


A) 2 g
B) 4 g
C) 6 g
D) 8 g

E) A) and C)
F) B) and D)

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Complete the following zig-zag structure so that it represents (2R,3S)-3-chlorobutan-2-ol. Complete the following zig-zag structure so that it represents (2R,3S)-3-chlorobutan-2-ol.

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Which of the following have the S configuration? Which of the following have the S configuration?   A) only 1 B) only 2 C) only 1 and 2 D) 1, 2 and 3


A) only 1
B) only 2
C) only 1 and 2
D) 1, 2 and 3

E) B) and C)
F) None of the above

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How many stereoisomers of 2,4-dimethylpentane, (CH3) 2CHCH2CH(CH3) 2, exist?


A) 1
B) 2
C) 3
D) 4

E) C) and D)
F) A) and B)

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Which of the following Newman projections represents (2R,3R) -dibromobutane? Which of the following Newman projections represents (2R,3R) -dibromobutane?   A) 1 B) 2 C) 3 D) 4


A) 1
B) 2
C) 3
D) 4

E) None of the above
F) All of the above

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______________ are stereoisomers that are not mirror images.

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Diastereom...

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Which of the following is the definition of chirality?


A) The non-superposability of an object on its mirror image
B) The superposability of an object on its mirror image
C) A molecule that has a carbon atom with four different substituents
D) A molecule with a mirror image

E) B) and C)
F) A) and C)

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The following structures depicts (__)-3-ethyl-2,3-dimethylhexane. The following structures depicts (__)-3-ethyl-2,3-dimethylhexane.

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Complete the following diagram so that it represents (S)-2-butanol. Complete the following diagram so that it represents (S)-2-butanol.

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Which of the following compounds is/are chiral? Which of the following compounds is/are chiral?   A) only 1 B) only 1 and 2 C) only 2 and 3 D) 1, 2 and 3


A) only 1
B) only 1 and 2
C) only 2 and 3
D) 1, 2 and 3

E) B) and D)
F) A) and B)

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Complete the following Newman projection so that it represents (2R,3S)-2,3-dibromobutane. Complete the following Newman projection so that it represents (2R,3S)-2,3-dibromobutane.

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Which of the following is the definition of a pair of diastereomers?


A) A pair of structures that are superposable mirror images of one another
B) A pair of stereoisomers that are non-superposable mirror images of one another
C) A pair of stereoisomers that are not mirror images of one another
D) A pair of stereoisomers that have equal specific rotations

E) A) and C)
F) C) and D)

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How many stereoisomers of 4-chloro-2-methylpentane (CH3) 2CHCH2CHClCH3, exist?


A) 1
B) 2
C) 3
D) 4

E) A) and D)
F) All of the above

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A natural product having [ α\alpha ]D = +40.3 ∘\circ has been isolated and purified. Either of the following substances could be this natural product.  A natural product having [ \alpha ]<sub>D</sub> = +40.3<sup> \circ </sup> has been isolated and purified. Either of the following substances could be this natural product.

A) True
B) False

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What is the correct order of the Cahn-Ingold-Prelog ranking of the following substituents as used in assigning R and S configurations of chiral centers? (higher ranking > lower ranking) 1.-C-CH 2.-CH2NH2 3.-NHCH3 4) -CN


A) 3 > 2 > 4 > 1
B) 4 > 3 > 1 > 2
C) 3 > 4 > 2 > 1
D) 4 > 3 > 2 > 1

E) All of the above
F) A) and C)

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Which of the following substituents has the highest priority according to the Cahn-Ingold-Prelog system used in assigning R and S configurations?


A) "-COOH"
B) "-CHO"
C) "-CH2OH"
D) "-CH3"

E) C) and D)
F) A) and C)

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The absolute configurations around C-2 and C-3 in the following Fischer projection are, respectively, ____. (Enter the two configurations separated by a comma.) The absolute configurations around C-2 and C-3 in the following Fischer projection are, respectively, ____. (Enter the two configurations separated by a comma.)

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Which of the following structures is different from the other three? Which of the following structures is different from the other three?   A) 1 B) 2 C) 3 D) 4


A) 1
B) 2
C) 3
D) 4

E) None of the above
F) B) and C)

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The process that separates enantiomers is called ______________.

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