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Complete the following diagram so that it represents (S)-2-butanol. Complete the following diagram so that it represents (S)-2-butanol.

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Which of the following structures is chiral? Which of the following structures is chiral?   A) 1 B) 2 C) 3 D) 4


A) 1
B) 2
C) 3
D) 4

E) A) and B)
F) A) and C)

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Which of the following is the definition of a meso compound?


A) A molecule with stereocenter centers which is chiral
B) A molecule with stereocenter centers which is not chiral
C) A diastereomer with no stereocenter centers
D) A chiral compound with more than one stereocenter center

E) None of the above
F) A) and B)

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The specific rotation of the S-enantiomer of a compound is -120ΒΊ. A student determines that a sample of the compound has a specific rotation of +60ΒΊ. What mass of the S-enantiomer is present in 10 g of the sample

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An unknown sample is tested with a polarimeter for optical activity. The results of the test required no movement of the analyzer. This sample could be either a meso compound or a racemic mixture.

A) True
B) False

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Which of the following is the definition of a pair of enantiomers?


A) A pair of structures that are superposable mirror images of one another
B) A pair of stereoisomers that are non-superposable mirror images of one another
C) A pair of stereoisomers that are not mirror images of one another
D) A pair of stereoisomers that have equal specific rotations

E) A) and D)
F) None of the above

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The specific rotation of enantiomers have the same magnitude.

A) True
B) False

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How many isomers (constitutional and stereoisomers) exist for dimethylpentane?


A) 2
B) 3
C) 4
D) 5

E) A) and D)
F) None of the above

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Of the compounds listed below, only 2 has a chiral centers. Of the compounds listed below, only 2 has a chiral centers.

A) True
B) False

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How many chiral centers are there in the following molecule (the naturally occurring stereoisomer is camphor, a pungent moth repellent) ? How many chiral centers are there in the following molecule (the naturally occurring stereoisomer is camphor, a pungent moth repellent) ?   A) Two B) Three C) Four D) Five


A) Two
B) Three
C) Four
D) Five

E) B) and C)
F) All of the above

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How much of the R enantiomer is present in 10 g of a mixture which has an enantiomeric excess of 20% of the S isomer?


A) 1 g
B) 2 g
C) 4 g
D) 6 g

E) None of the above
F) A) and C)

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Which of the following substituents has the highest priority according to the Cahn-Ingold-Prelog system used in assigning R and S configurations?


A) "-NH2"
B) "-NHCH3"
C) "-CH2NH2"
D) "-CH2NHCH3"

E) None of the above
F) B) and D)

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What mass of (S)-(-)-mandelic acid is present in a 10 g sample which has an enantiomeric excess of 20% of the S-enantiomer?

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