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Exam 17: Carboxylic Acids

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Question 21

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Consider the data in the Table below to answer the following question: Acidities of Substituted Benzoic and Acetic Acids pK_as at 25 ^$\circ$ C Y-C₆H₄COOH Y Y-CH₂COOH meta para H 4.75 4.19 4.19 CN 2.47 3.64 3.55 OCH₃ 3.57 4.09 4.46 The structure of the acid with the strongest conjugate base in the table above is CH₃COOH.

A) True
B) False

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Question 22

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Which of the following has the highest boiling point?

A) hexane
B) 1-pentanol
C) pentanal
D) butanoic acid

E) A) and B)
F) A) and C)

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Question 23

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The structure of cis-1,3-cyclopentanedicarboxylic acid is shown below.

What is the major organic product obtained from the following sequence of reactions?

Which of the following carboxylic acids undergoes the most rapid thermal decarboxylation reaction?

What is the major organic product obtained from the following reaction?

Which of the following is the correct order of decreasing acid strength (more acidic > less acidic) ?

Which of the following has the highest boiling point?

Which of the following is the correct order of decreasing acid strength (more acidic > less acidic) ?

Based on the informaton presented below, answer the following questions. An ether solution contains the following components. 2,3,4,5-tetramethylbenzene benzyl alcohol 2-hydroxybenzoic acid This solution is extracted with a 1.0 M solution of NaOH, that is immiscible with ether. -The 2-hydroxybenzoic acid will be recovered from the _______ layer.

What is the major organic product obtained from the following reaction?

What is the IUPAC name of the following compound?

What is the IUPAC name of the following compound

Based on the informaton presented below, answer the following questions. An ether solution contains the following components. 2,3,4,5-tetramethylbenzene benzyl alcohol 2-hydroxybenzoic acid This solution is extracted with a 1.0 M solution of NaOH, that is immiscible with ether. -The 2,3,4,5-tetramethylbenzene will be recovered from the _______ layer.

What is the correct assignment of the names of the following substituted benzenes?

Consider the following reaction. The major organic product obtained is

What is the major organic product obtained from the following reaction?

The strongest acid of the following is indicated by the Roman numeral ______.

What is the IUPAC name of the following compound?

Provide the correct name for the following compound which can be used to produce aspirin.