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Predict the major product when p-toluidine reacts with sodium nitrite and hydrochloric acid at < 5°C followed by o-ethylphenol? 2

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What is the common name for the following compound? What is the common name for the following compound? A) dibenzylamine B) diphenylamine C) dibenzeneamine D) phenylbenzeneamine E) none of these


A) dibenzylamine
B) diphenylamine
C) dibenzeneamine
D) phenylbenzeneamine
E) none of these

F) A) and B)
G) All of the above

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Which one of the following is the best synthesis for 3,5-dibromotoluene?


A) toluene, Br2/FeBr3 excess
B) 1. p-toluidine, Br2/ FeBr3;
2) NaNO2/HCl, < 5°C
3) H3PO2
C) 1. Toluene, HNO3/H2SO4
2) NH3
3) NaNO2/HCl, < 5°C
4) CuBr
D) m-dibromobenzene, CH3Cl/AlCl3
E) 1. m-bromotoluene, HNO3, H2SO4
2) Fe/HCl
3) NaNO2/HCl, < 5°C
4) CuBr

F) B) and D)
G) A) and E)

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What is the IUPAC name for the following compound? What is the IUPAC name for the following compound? A) ethylisobutylisopropylamine B) ethylisopropylbutylamine C) sec-butylethylpropylamine D) sec-butylethylisopropylamine E) none of these


A) ethylisobutylisopropylamine
B) ethylisopropylbutylamine
C) sec-butylethylpropylamine
D) sec-butylethylisopropylamine
E) none of these

F) A) and E)
G) A) and B)

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Provide the reagents necessary to carry out the following conversion for the following reaction. Provide the reagents necessary to carry out the following conversion for the following reaction.

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Predict the product for the following reaction. Predict the product for the following reaction. A) I B) II C) III D) IV E) V Predict the product for the following reaction. A) I B) II C) III D) IV E) V Predict the product for the following reaction. A) I B) II C) III D) IV E) V


A) I
B) II
C) III
D) IV
E) V

F) C) and E)
G) C) and D)

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What is the IUPAC name for the following compound? What is the IUPAC name for the following compound?

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7-amino-5-...

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Arrange the following compounds in increasing (weakest to strongest) order of basicity. Arrange the following compounds in increasing (weakest to strongest) order of basicity. A) IV < II < I < III B) III < II < IV < I C) II < I < III < IV D) II < III < I < IV E) None of the above


A) IV < II < I < III
B) III < II < IV < I
C) II < I < III < IV
D) II < III < I < IV
E) None of the above

F) C) and D)
G) A) and B)

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C

Provide the reagents necessary to carry out the following conversion. Provide the reagents necessary to carry out the following conversion.

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1. blured image_TB4454...

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What is the IUPAC name for the following compound? What is the IUPAC name for the following compound?

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7-amino-5-ethyl-1-hydroxy-3-octanone

A compound with molecular formula C8H11N displays the following IR, 1H NMR and 13C NMR spectra. Propose a structure for this compound. A compound with molecular formula C<sub>8</sub>H<sub>11</sub>N displays the following IR, <sup>1</sup>H NMR and <sup>13</sup>C NMR spectra. Propose a structure for this compound. SDBS A compound with molecular formula C<sub>8</sub>H<sub>11</sub>N displays the following IR, <sup>1</sup>H NMR and <sup>13</sup>C NMR spectra. Propose a structure for this compound. SDBS SDBS A compound with molecular formula C<sub>8</sub>H<sub>11</sub>N displays the following IR, <sup>1</sup>H NMR and <sup>13</sup>C NMR spectra. Propose a structure for this compound. SDBS

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Arrange the following compounds in decreasing (strongest to weakest) order of basicity. Arrange the following compounds in decreasing (strongest to weakest) order of basicity. A) I > III > II > IV B) II > III > I > IV C) IV > II > I > III D) IV > III > II > I E) II > I > IV > III


A) I > III > II > IV
B) II > III > I > IV
C) IV > II > I > III
D) IV > III > II > I
E) II > I > IV > III

F) A) and B)
G) A) and E)

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Provide a stepwise synthesis to carry out the following conversion. Provide a stepwise synthesis to carry out the following conversion.

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blured image_TB4454_00...

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Predict the product for the following reaction. Predict the product for the following reaction.

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Which of the following compounds is the strongest base? Which of the following compounds is the strongest base? A) I B) II C) III D) IV E) V Which of the following compounds is the strongest base? A) I B) II C) III D) IV E) V


A) I
B) II
C) III
D) IV
E) V

F) A) and C)
G) C) and E)

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Predict the product for the following reaction and provide a stepwise, curved arrow mechanism for the formation of the product. Predict the product for the following reaction and provide a stepwise, curved arrow mechanism for the formation of the product.

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blured image_TB4454_00...

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Nicotine, present in tobacco, has the following structure. Which nitrogen is more basic and explain your choice. Nicotine, present in tobacco, has the following structure. Which nitrogen is more basic and explain your choice.

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N2 is more basic as ...

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Which of these alkyl halides cannot be used to prepare amines using Gabriel synthesis?


A) 1-bromopentane
B) 1-bromo-3-methylbutane
C) 2-bromo-3-methylpentane
D) 1-bromo-2,3-dimethylbutane
E) 2-bromo-2,3-dimethylbutane

F) B) and C)
G) D) and E)

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A compound with molecular formula C7H17N exhibits a triplet at δ\delta 1.0 (3H), a doublet at δ\delta 1.1 (I=6), a multiplet at δ\delta 2.0 (1H), a singlet at δ\delta 2.3 (3H), a doublet at δ\delta 2.3 (2H), and a quartet at δ\delta 2.4 (2H) in its 1H NMR spectrum. Its 13C NMR spectrum showed peaks at δ\delta 13.4, δ\delta 20, δ\delta 27.9, δ\delta 39.3, δ\delta 49.5 and δ\delta 65.2. What is the structure for this compound?

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11ea894b_ad55_91ce_bba7_9123d1749079_TB4454_00_TB4454_00

What is the IUPAC name for the following compound? What is the IUPAC name for the following compound? A) N-ethylhexanamine B) N-ethylcyclohexanamine C) N-cyclohexylethanamine D) N-ethylcyclopentanamine E) N-ethylaniline


A) N-ethylhexanamine
B) N-ethylcyclohexanamine
C) N-cyclohexylethanamine
D) N-ethylcyclopentanamine
E) N-ethylaniline

F) A) and B)
G) C) and D)

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