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A compound with molecular formula C4H11N exhibits a triplet at δ\delta 0.9 (I=3), a doublet at δ\delta 1.1 (I=3), a quintet at δ\delta 1.4 (I=2), a singlet at δ\delta 1.7 (I=2) and a sextet at δ\delta 2.8 (I=2) in its 1HNMR spectrum. Its IR spectrum shows two medium absorption bands near 3400 cm-1. What is the structure for this compound?

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Predict the product for the following reaction. Predict the product for the following reaction.       A)  I B)  II C)  III D)  IV E)  III & IV Predict the product for the following reaction.       A)  I B)  II C)  III D)  IV E)  III & IV Predict the product for the following reaction.       A)  I B)  II C)  III D)  IV E)  III & IV


A) I
B) II
C) III
D) IV
E) III & IV

F) A) and B)
G) All of the above

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Which of the following compounds is the strongest base? Which of the following compounds is the strongest base?   A)  I B)  II C)  III D)  IV E)  V


A) I
B) II
C) III
D) IV
E) V

F) A) and C)
G) A) and E)

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A compound with molecular formula C7H17N exhibits a triplet at δ\delta 1.0 (I=3), a doublet at δ\delta 1.1 (I=6), a multiplet at δ\delta 2.0 (I=1), a singlet at δ\delta 2.3 (I=3), a doublet at δ\delta 2.3 (I=2), and a quartet at δ\delta 2.4 (I=2) in its 1HNMR spectrum. Its 13CNMR spectrum showed peaks at δ\delta 13.4, 20, 27.9, 39.3, 49.5 and 65.2. What is the structure for this compound?

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Predict the major product for the following reaction. Predict the major product for the following reaction.     A)  I B)  II C)  III D)  IV E)  V Predict the major product for the following reaction.     A)  I B)  II C)  III D)  IV E)  V


A) I
B) II
C) III
D) IV
E) V

F) None of the above
G) A) and D)

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Provide a stepwise synthesis of 1-cyclopentylethanamine using the Gabriel synthesis.

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Provide the reagents necessary to carry out the following conversion. Provide the reagents necessary to carry out the following conversion.

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What is the common name for the following compound? What is the common name for the following compound?   A)  ethylisobutylisopropylamine B)  ethylisopropylbutylamine C)  sec-butylethylpropylamine D)  sec-butylethylisopropylamine E)  none of these


A) ethylisobutylisopropylamine
B) ethylisopropylbutylamine
C) sec-butylethylpropylamine
D) sec-butylethylisopropylamine
E) none of these

F) D) and E)
G) C) and E)

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Arrange the following compounds in decreasing (strongest to weakest) order of basicity. Arrange the following compounds in decreasing (strongest to weakest)  order of basicity.   A)  I>III>II>IV B)  II>III>I>IV C)  IV>III>II>I D)  IV>I>II>III E)  II>I>IV>III


A) I>III>II>IV
B) II>III>I>IV
C) IV>III>II>I
D) IV>I>II>III
E) II>I>IV>III

F) B) and C)
G) B) and E)

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Provide the reagents necessary to carry out the following conversion. Provide the reagents necessary to carry out the following conversion.

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1. NaNO2/HCl/<50C
2. C...

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What is the IUPAC name for the following compound? What is the IUPAC name for the following compound?

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(1R,6R)-6-...

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Predict the major product for the following reaction. Predict the major product for the following reaction.     A)  I B)  II C)  III D)  IV E)  I & III Predict the major product for the following reaction.     A)  I B)  II C)  III D)  IV E)  I & III


A) I
B) II
C) III
D) IV
E) I & III

F) C) and E)
G) A) and B)

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What is the common name for the following compound? What is the common name for the following compound?   A)  ethylethylisobutylamine B)  diethylisobutylamine C)  sec-butyldiethylamine D)  2-diethylaminobutane E)  none of these


A) ethylethylisobutylamine
B) diethylisobutylamine
C) sec-butyldiethylamine
D) 2-diethylaminobutane
E) none of these

F) B) and D)
G) B) and E)

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What is the IUPAC name for the following compound? What is the IUPAC name for the following compound?

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7-amino-5-...

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Predict the product for the following reaction. Predict the product for the following reaction.       A)  I B)  II C)  III D)  IV E)  none of these Predict the product for the following reaction.       A)  I B)  II C)  III D)  IV E)  none of these Predict the product for the following reaction.       A)  I B)  II C)  III D)  IV E)  none of these


A) I
B) II
C) III
D) IV
E) none of these

F) A) and B)
G) A) and C)

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Provide the reagents necessary to carry out the following conversion. Provide the reagents necessary to carry out the following conversion.

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1. NaNO2/HC...

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Which of these alkyl halides cannot be used to prepare amines using Gabriel synthesis?


A) 1-bromopentane
B) 1-bromo-3-methylbutane
C) 2-bromo-3-methylpentane
D) 1-bromo-2,3-dimethylbutane
E) 2-bromo-2,3-dimethylbutane

F) A) and C)
G) C) and D)

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What is the IUPAC name for the following compound? What is the IUPAC name for the following compound?   A)  N-ethylhexanamine B)  N-ethylcyclohexanamine C)  N-cyclohexylethanamine D)  N-ethylcyclopentanamine E)  N-ethylaniline


A) N-ethylhexanamine
B) N-ethylcyclohexanamine
C) N-cyclohexylethanamine
D) N-ethylcyclopentanamine
E) N-ethylaniline

F) A) and D)
G) D) and E)

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Pyridoxamine, aka vitamin B6 has the following structure. Which nitrogen is more basic? Explain your choice. Pyridoxamine, aka vitamin B<sub>6</sub> has the following structure. Which nitrogen is more basic? Explain your choice.

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N1 is more basic as it is sp3 h...

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Classify the following compounds as a primary, secondary or tertiary amine. Classify the following compounds as a primary, secondary or tertiary amine.

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I-secondary amine
II...

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